{1364} revision 0 modified: 01-22-2017 05:51 gmt

Aqueous degradation of polyimides

  • Above ph 2, Kapton (PMDA-ODA) test specimens decreased both tensile strength and elongation to break with water, with a rate that increased with temperature.
  • No samples completely degraded, however; tensile strength decreased by about 2x, and elongation from 30% to 5%.
  • The authors suspect that ortho (off-molecular axis) amide bonding, at about 0.6% of the total number of imide bonds, is responsible for this (otherwise the film would completely fall apart.)
  • Imide bonds themselves are robust to all but strong bases and acids.
  • See also {1253}.